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Questions Available: 19
Year: 2023
Topic: Solutions
1.
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R :
Assertion A: Helium is used to dilute oxygen in diving apparatus.
Reason R: Helium has high solubility in O2
In the light of the above statements, choose the correct answer from the options given below:
(1).
Both A and R are true but R is NOT the correct explanation of A.
(2).
A is true but R is false.
(3).
A is false but R is true.
(4).
Both A and R are true and R is the correct explanation of A.

Year: 2025
Topic: Solutions
2.
Which of the following aqueous solution will exhibit highest boiling point?
(1).
\(\text{0.015M}\,C_6H_12O_6\)
(2).
\(\text{0.01M Urea}\)
(3).
\(\text{0.01M}\, KNO_3\)
(4).
\(\text{0.01M}\, Na_2SO_4\)

Year: 2025
Topic: Solutions
3.
Match List - I with List - II

Choose the correct answer from the options given below :
(1).
A-III, B-II, C-I, D-IV
(2).
A-II, B-IV, C-I, D-III
(3).
A-II, B-I, C-IV, D-III
(4).
A-III, B-I, C-IV, D-II

Year: 2025
Topic: Solutions
4.
5 moles of liquid X and 10 moles of liquid Y make a solution having a vapour pressure of 70 torr. The vapour pressures of pure X and Y are 63 torr and 78 torr respectively, Which of the following is true regarding the described solution?
(1).
The solution has volume greater than the sum of individual volumes.
(2).
The solution shows positive deviation.
(3).
The solution shows negative deviation.
(4).
The solution is ideal.

Year: 2024
Topic: Solutions
5.
The plot of osmotic pressure (\(\pi\)) vs concentration (\(\text{mol L}^{-1}\)) for a solution gives a straight line with slope \(25.73\,\text{L bar mol}^{-1}\). The temperature at which the osmotic pressure measurement is done is
(Use \(\text{R}\,=\, 0.083\,\text{L bar mol}^{-1}\text{K}^{-1}\))
(1).
\(25.73^\circ\,\text{C}\)
(2).
\(12.05^\circ\,\text{C}\)
(3).
\(37^\circ\,\text{C}\)
(4).
\(310^\circ\,\text{C}\)

Year: 2024
Topic: Solutions
6.
The Henry's law constant \(\left(\text{K}_\text{H}\right)\) values of three gases (A, B, C) in water are \(145\), \(2 \times 10^{-5}\) and \(35\) kbar, respectively. The solubility of these gases in water follow the order:
(1).
A > C > B
(2).
A > B > C
(3).
B > A > C
(4).
B > C > A

Year: 2021
Topic: Solutions
7.
The following solutions were prepared by dissolving 10 g of glucose (C6H12O6) in 250 ml of water (P1), 10 gof urea (CH4N2O) in 250 ml of water (P2) and 10 g of sucrose (C12H22O11) in 250 ml of water (P3). The right option for the decreasing order of osmotic pressure of these solutions is :
(1).
P2 > P1 > P3
(2).
P1 > P2 > P3
(3).
P2 > P3 > P1
(4).
P3 > P1 > P2

Year: 2021
Topic: Solutions
8.
The correct option for the value of vapour pressure of a solution at 45°C with benzene to octane in molar ratio 3: 2 is :
[At 45°C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg, Assume Ideal gas]
(1).
160 mm of Hg
(2).
168 mm of Hg
(3).
336 mm of Hg
(4).
350 mm of Hg

Year: 2020
Topic: Solutions
9.
The mixture which shows positive deviation from Raoult's law is:
(1).
Benzene + Toluene
(2).
Acetone + Chloroform
(3).
Chloroethane + Bromoethane
(4).
Ethanol+Acetone

Year: 2020
Topic: Solutions
10.
Find out the solubility of Ni(OH)2 in 0.1 M NaOH. Given that the ionic product of Ni(OH)2 is 2 x 10-15
(1).
2 x 10-8 M
(2).
1 x 10-13 M
(3).
1 x 108 M
(4).
2 x 10-13 M

Year: 2020
Topic: Solutions
11.
The freezing point depression constant (Kf) of benzene is 5.12 K kg mol-1. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is
(rounded off up to two decimal places):
(1).
0.80 K
(2).
0.40 K
(3).
0.60 K
(4).
0.20 K

Year: 2020
Topic: Solutions
12.
HCl was passed through a solution of CaCI2, MgCi2 and NaCI. Which of the following compound(s) crystallise(s)?
(1).
Only NaCI
(2).
Only MgCl2
(3).
NaCI, MgCl2 and CaCl2
(4).
Both MgCl2 and CaCl2

Year: 2019
Topic: Solutions
13.
The mixture that forms maximum boiling azeotrope is
(1).
Ethanol + Water
(2).
Acetone + Carbon disulphide
(3).
Heptane + Octane
(4).
Water + Nitric acid

Year: 2019
Topic: Solutions
14.
For an ideal solution, the correct option is
(1).
\(\Delta_{mix}\) V \(\neq\) 0 at constant T and P
(2).
\(\Delta_{mix}\) H = 0 at constant T and P
(3).
\(\Delta_{mix}\) G = 0 at constant T and P
(4).
\(\Delta_{mix}\) S = 0 at constant T and P

Year: 2017
Topic: Solutions
15.
For a given reaction, \(\Delta \text{H}\) = 35.5 kJ mol–1 and \(\Delta \text{S}\) = 83.6 JK–1 mol–1. The reaction is spontaneous at :
[Assume that \(\Delta \text{H}\) and \(\Delta \text{S}\) do not vary with temperature]
(1).
T > 298 K
(2).
T < 425 K
(3).
T > 425 K
(4).
All temperatures

Year: 2017
Topic: Solutions
16.
If molality of the dilute solution is doubled, the value of molal depression constant (Kf ) will be
(1).
unchanged.
(2).
doubled.
(3).
halved.
(4).
tripled.

Year: 2017
Topic: Solutions
17.
Which of the following is dependent on temperature ?
(1).
Weight percentage
(2).
Molality
(3).
Molarity
(4).
Mole fraction

Year: 2016
Topic: Solutions
18.
At 100°C the vapour pressure of a solution of 6.5 g of a solute in 100 g water is 732 mm. If Kb = 0.52, the boiling point of this solution will be
(1).
100°C
(2).
102°C
(3).
103°C
(4).
101°C

Year: 2016
Topic: Solutions
19.
Which of the following statements about the composition of the vapour over an ideal 1 : 1 molar mixture of benzene and toluene is correct ? Assume that the temperature is constant at 25 ° C.
( Given , vapour pressure data at 25 ° C , benzene = 12.8 kPa , toluene = 3.85 kPa )
(1).
The vapour will contain a higher percentage of toluene
(2).
The vapour will contain equal amounts of benzene and toluene
(3).
Not enough information is given to make a prediction
(4).
The vapour will contain a higher percentage of benzene